??? ??? ?? ???, ?? ?? ??? ??? ???? ????????? ??
- ??? ???????(Nature Communications)? 5? 8? ??
▲ ??? ?????(?1??, ??)? ??? ??(????, ???)
??? ??? ?? ???? ?? ?? ??? ???? ??? ???? ‘?????????(Aquaphotocatalysis)’? ??? ?????. ???? ??? ?? ??? ?????? ??? ?????? ??? ????? ?????? ???? ??? ???? ?????.
????? ??????? ???, ????, 2??? ?????? ? ??? ???? ???? ??? ?? ?????. ???? ??? ? ?? ??? ??? ?? ???? ???(covalent inhibitor)?? ???? ??. ? ???? ??? ????? ???(Sulfur(VI)–Fluoride Exchange: SuFEx)? ?????, ??? ??? ??? ??? ??? ? ?? ????? ????.
?? ????? ?????? ???? ???? ?? ???? ??????, ??? ?? ???? ??? ??? ???? ???? ????? ?? ??? ???? ?????? ????? ??? ? ??. ???? ??-????? ??????? ??? ??? ??? ??? ???? ????? ??????? ?? ??? ?????.
??, ???? ???? ??????? ?? ??? ‘????’?? ???? ?????, ?? ???? ???? ??? ???? ??? ??? ?????. ? ??? ???? ????? ?? ????? ???? ????, ??????, ??? ?? ????? ???? ????? ?????*? ?? ? ????, ?? ? ??? ??????? ??? ? ??? ?????.
* ????? ?????: ?? ???? ???(aromaticity)? ????? ??? ????? ?? ???? ???
??? ??? “????? ???? ??? ?? ?? ??? ?? ??? ?? ????? ????? ???? ??? ???? ????. ?????? ????? ???? ??? ?? ?? ?? ?? ????? ??? ??? ? ?, ????(Biomimicry)? ??? ????? ??? ??? ??”??? ???.
??? “??? ????? 2??? ??????, ???? ??? ???? ? ??? ?? ? ??????? ?? ??? ?”??? ???.
???? ?? ????? ??? ??? ???? ??? ???????(Nature Communications)? 5? 8? ?????.
※ ????: “On-Water” Accelerated Dearomative Cycloaddition via Aquaphotocatalysis
※ ??: Nature Communications
※
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